- Which of these is a chemical change?
- Melting of ice
- Milk turning into curd
- Sublimation of camphor
- Dissolving salt
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Answer: (B) Milk turning into curd
Curd contains a new substance (lactic acid) and the change does not reverse — the other three are physical changes.
- On balancing Fe + H₂O ⟶ Fe₃O₄ + H₂, the coefficient of H₂O is?
- 2
- 3
- 6
- 4
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Answer: (D) 4
3Fe + 4H₂O → Fe₃O₄ + 4H₂ — 4H₂O for the 4 oxygens of Fe₃O₄.
- Pouring water on quicklime is which type of reaction?
- Combination and exothermic
- Decomposition
- Displacement
- Endothermic
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Answer: (A) Combination and exothermic
CaO + H₂O → Ca(OH)₂ — two substances make one, and a lot of heat comes out.
- Which reaction happens in black-and-white photography?
- Thermal decomposition of AgBr
- Electrolysis of AgNO₃
- Photolysis of AgBr
- Oxidation of Ag
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Answer: (C) Photolysis of AgBr
2AgBr → 2Ag + Br₂ in light; black silver grains wherever light fell.
- Colour of the precipitate on mixing Pb(NO₃)₂ and KI solutions?
- White
- Blue
- Yellow
- Black
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Answer: (C) Yellow
Pb(NO₃)₂ + 2KI → PbI₂↓ (bright yellow) + 2KNO₃ — double displacement/precipitation.
- An iron nail in CuSO₄ solution — colour of the solution?
- Blue to pale green
- Green to blue
- Colourless to blue
- No change
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Answer: (A) Blue to pale green
Fe + CuSO₄ → FeSO₄ (pale green) + Cu — iron is more reactive than copper.
- In CuO + H₂ → Cu + H₂O, the oxidising agent is?
- H₂
- H₂O
- Cu
- CuO
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Answer: (D) CuO
CuO gives oxygen and oxidises H₂, and is itself reduced to Cu.
- By the electronic definition, oxidation is —
- Gain of electrons
- Loss of electrons
- Gain of protons
- Loss of neutrons
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Answer: (B) Loss of electrons
OIL RIG — Oxidation Is Loss of electrons; reduction is gain.
- Oxidation number of Cr in K₂Cr₂O₇?
- +6
- +3
- +7
- +12
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Answer: (A) +6
2(+1) + 2x + 7(−2) = 0 → x = +6.
- Which of these is a disproportionation reaction?
- 2H₂ + O₂ → 2H₂O
- Zn + CuSO₄ → ZnSO₄ + Cu
- Cl₂ + 2NaOH → NaCl + NaOCl + H₂O
- HCl + NaOH → NaCl + H₂O
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Answer: (C) Cl₂ + 2NaOH → NaCl + NaOCl + H₂O
Cl goes from 0 to −1 (NaCl) and +1 (NaOCl) — the same element in both directions.
- Average oxidation number of iron in Fe₃O₄?
- +2
- +8/3
- +3
- +4
Show answer
Answer: (B) +8/3
3x − 8 = 0 → 8/3; really one Fe²⁺ and two Fe³⁺.
- Photosynthesis is which type of reaction?
- Exothermic
- Displacement
- Neutralisation
- Endothermic
Show answer
Answer: (D) Endothermic
The plant absorbs the Sun’s energy to make glucose (ΔH ≈ +2808 kJ/mol); respiration is its reverse, exothermic.
- Why is nitrogen filled in chips packets?
- For taste
- To add moisture
- To add weight
- To stop rancidity (oxidation)
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Answer: (D) To stop rancidity (oxidation)
N₂ is inert; with no oxygen the fat is not oxidised (no staleness).
- Unit of rate of reaction?
- mol L⁻¹
- mol L⁻¹ s⁻¹
- s⁻¹
- L mol⁻¹
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Answer: (B) mol L⁻¹ s⁻¹
Change in concentration ÷ time = mol L⁻¹ s⁻¹; s⁻¹ is the unit of k for first order.
- The half-life of a first-order reaction is —
- Proportional to starting concentration
- Inversely proportional to concentration
- Independent of starting concentration
- Always 1 hour
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Answer: (C) Independent of starting concentration
t½ = 0.693/k — no concentration in it; radioactive decay is the example.
- A first-order reaction has t½ = 20 minutes. How much is left after 80 minutes?
- 6.25%
- 12.5%
- 25%
- 50%
Show answer
Answer: (A) 6.25%
80/20 = 4 half-lives → (½)⁴ = 1/16 = 6.25%.
- Which of these can be zero or a fraction?
- Molecularity
- Order
- Both
- Neither
Show answer
Answer: (B) Order
Order comes from experiment (0, ½, 1.5…); molecularity is always a whole number.
- Raising the temperature by 10 °C makes the rate of most reactions —
- Half
- Unchanged
- Ten times
- About double
Show answer
Answer: (D) About double
Temperature coefficient 2–3; the molecules with energy above Eₐ nearly double.
- Which statement about a catalyst is correct?
- It lowers the activation energy
- It lowers ΔH
- It raises the equilibrium constant
- It speeds up only the forward reaction
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Answer: (A) It lowers the activation energy
A catalyst gives a path of lower Eₐ; forward and backward speed up equally, so K and ΔH stay the same.
- Relation of Kp and Kc for N₂ + 3H₂ ⇌ 2NH₃?
- Kp = Kc
- Kp = Kc(RT)²
- Kp = Kc(RT)⁻²
- Kp = Kc(RT)
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Answer: (C) Kp = Kc(RT)⁻²
Δn = 2 − 4 = −2, so Kp = Kc(RT)⁻².
- By Le Chatelier, raising the pressure in the Haber process —
- Lowers NH₃
- Has no effect
- Raises NH₃
- Raises K
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Answer: (C) Raises NH₃
The equilibrium shifts to fewer gas moles (2 mol NH₃); K changes only with temperature.
- Promoters used with the iron catalyst in the Haber process?
- K₂O and Al₂O₃
- V₂O₅
- Pt
- As₂O₃
Show answer
Answer: (A) K₂O and Al₂O₃
K₂O and Al₂O₃ raise the activity of iron; As₂O₃ is a poison in the Contact process.
- Correct statement about physical adsorption?
- Only one layer
- Irreversible
- Highly specific
- By van der Waals forces, many layers
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Answer: (D) By van der Waals forces, many layers
Physical adsorption is by weak forces, reversible, multi-layer and falls as temperature rises.
- Standard EMF of the Daniell cell?
- 0.76 V
- 1.10 V
- 1.36 V
- 2.00 V
Show answer
Answer: (B) 1.10 V
E° = 0.34 − (−0.76) = 1.10 V; Zn anode, Cu cathode.
- In a galvanic cell the anode is —
- Negative, oxidation
- Positive, reduction
- Positive, oxidation
- Negative, reduction
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Answer: (A) Negative, oxidation
In a galvanic cell the anode is negative; oxidation is at the anode in every cell.
- Strongest reducing agent in water?
- Na
- K
- Li
- Cs
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Answer: (C) Li
Li has the most negative E° (−3.05 V) — the small Li⁺ has a very large hydration energy.
- CuSO₄ solution can be kept safely in a vessel of which metal?
- Zinc
- Silver
- Nickel
- Iron
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Answer: (B) Silver
Ag (+0.80 V) cannot displace Cu²⁺ (+0.34 V); Zn, Fe and Ni can.
- The factor in the Nernst equation at 298 K is —
- 96500/n
- 0.693/n
- 2.303/n
- 0.0591/n
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Answer: (D) 0.0591/n
E = E° − (0.0591/n) log Q.
- On dilution of an electrolyte —
- Both κ and Λm rise
- Both fall
- κ rises, Λm falls
- κ falls, Λm rises
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Answer: (D) κ falls, Λm rises
With fewer ions per cm³ κ falls, but ions move more freely so Λm rises.
- How much silver does 1 faraday of charge deposit?
- 54 g
- 108 g
- 216 g
- 10.8 g
Show answer
Answer: (B) 108 g
Ag⁺ + e⁻ → Ag; 1 mol e⁻ = 1 F = 1 mol Ag = 108 g.
- 2 A for 965 s through CuSO₄ — copper deposited?
- 0.3175 g
- 1.27 g
- 0.635 g
- 6.35 g
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Answer: (C) 0.635 g
Q = 1930 C = 0.02 F → 0.01 mol Cu × 63.5 = 0.635 g.
- In the electrolysis of brine, what forms at the cathode?
- Hydrogen
- Chlorine
- Sodium
- Oxygen
Show answer
Answer: (A) Hydrogen
In water solution, water is reduced instead of Na⁺: 2H₂O + 2e⁻ → H₂ + 2OH⁻.
- Why does a mercury cell keep a steady voltage all its life?
- Mercury is a liquid
- No ions in the overall reaction
- Zinc does not run out
- It contains acid
Show answer
Answer: (B) No ions in the overall reaction
Zn + HgO → ZnO + Hg — no ion whose concentration changes, so ≈ 1.35 V stays steady.
- As a lead–acid battery discharges —
- The acid’s density rises
- H₂SO₄ forms
- PbO₂ increases
- The acid’s density falls
Show answer
Answer: (D) The acid’s density falls
Pb + PbO₂ + 2H₂SO₄ → 2PbSO₄ + 2H₂O — the acid is used up and water forms.
- In the Contact process, SO₃ is absorbed in —
- 98% H₂SO₄
- Water
- Dilute HCl
- NaOH
Show answer
Answer: (A) 98% H₂SO₄
SO₃ + H₂SO₄ → H₂S₂O₇ (oleum); water would form a dense acid mist.
- Why does galvanising protect iron even when scratched?
- Zinc is less reactive
- Zinc is shiny
- Zinc is more reactive and corrodes first
- Zinc absorbs water
Show answer
Answer: (C) Zinc is more reactive and corrodes first
Zinc becomes the sacrificial anode; with tinning the iron rusts fast once scratched.
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